Iron : Blast Furnace
1) raw materials (Top)
iron ore
iron(III) oxide
coke
carbon source
reduction agent
limestone
remove impurities
slag
2) Hot air - bottom
3) coke: C(s) + air: O2(g) ---> CO2(g)
4) coke: C(s) + CO2(g) ---> 2CO (g)
5) Iron III oxide reduced
looses oxygen
Fe2O3(s) + 3CO(g) ---> 2Fe(l) + 3CO2(g)
6) molten iron run off : bottom
7) Limestone broken down in heat
CaCO3(s) --> CaO(s) + CO2 (g)
8) CaO(s) + SiO2(s) impurity/sand ---> CaSiO3 (l) slag
tapped off bottom
removal of impurities
reduction of iron ore 2FeO3(s) + 3C ---> 4Fe + 3CO2
Steel
from iron
iron
high carbon content (coke)
brittle
corrodes easily
rusting
iron + water + oxygen
protection
galvanising
cover iron in zinc
sacrificial protection
Alloying
mix iron with other metals to make steel
Carbon in molten iron (pig iron) + O2 ---> CO2
steel
0.1-1.5% carbon
more corrosion resistant
less brittle
uses dependent on carbon content
low carbon <0.3%
car bodies
medium carbon (0.3-0.9%)
rail tracks
high carbon (0.9-1.5%)
knives
stainless steel
add metals
chromium
nickle
vanadium
high pressure, hard wearing industrial tools
cobalt
Zinc
source
ZnS
zinc blend
ZnCO3
calamine
stage 1
zinc sulphide + oxygen ---> zinc oxide + sulphur dioxide
2ZnS(s) + 3O2 (g) ---> 2ZnO(s) + 2SO2 (g)
2 different stage 2's
reduction in blast furnace
ZnO(s) + CO(g) ---> Zn(l) + CO2 (g)
liquid zinc purified by frational distillation
oxide dissolved in sulphuric acid
ZnO(s) + H2SO4(aq) ---> ZnSO4(aq) + H2O
zinc sulphate electrolyised
cathode
made of pure zinc
Zn 2+ (aq) + 2e- ---> Zn(s)
annode
carbon
Subtopic 3
Chromium
thermite process
chromium (III) oxide
heat in electric arc furnace
+ silicon & calcium oxide
2Cr2O3 + 3Si + 3CaO ---> 4Cr + 3CaSiO3
calcium silicate
metal uses
aluminium
light
aircraft
iron
strong, malleable
car bodies, cutlery
zinc
low melting point
galvanising iron
chromium
very strong, corrosion resistant
stainless steel
copper
very good conductor electricity
electric wiring