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THERMOCHEMISTRY
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Important terms
- enthalpy of reaction
- calorimeter
- heat capacity
- system
- surroundings
- endothermic process
- enthalpy
- heat
- heat of reaction
- exothermic process
- Hess's law of heat summation
- standard state
- standard enthalpies (heat) of formation
- THERMOCHEMISTRY - Important terms.pdf
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Key equations
- Thermochemistry - key equations.pdf
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ATOMIC STRUCTURE
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what is light?
- it's a kind of energy
- each color of light have different energy
- האור מאטום מימן (מהשמיים) אינו רציף
- מכאן שהאור מורכב משני מרכיבים, חשמלי ומגנטי, ולכן נקרא אלקטרומגנטי
- אורך הגל ג
- הגודל שעולה ויורד הוא המרכיב החשמלי E
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V=c/ג
- c=3X10^10
- c=speed of light (constant)
- v = frequency of light
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E=hv=hc/ג
- h=6.63X10^-34 J/sec
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when ג is greater, E is smaller; opposely proportional :)
- but when v is greater E is also greater
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רמות אנרגיה
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n = 1,2,3...
- מס' הקוונטום הראשי
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l = 0,1,2... n-1
- מסי הקווטום האורביטלי
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m= +1, -1... +1
- מסי הקוונטם המגנטי
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Electron afinity
- is the energy change for the process of adding an electron to a neutral atom in the gaseous state to form a negative ion.
- The negative value actually means the energy released by the atom when it gains an electron
- large negative number indicates a very stable negative ion is formed
- higher electron affinity means smaller negative value
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Electronegativity
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ability of an atom in a molecule to draw bonding electrons to itself
- low ionization energy and low electron affinity means it has tendency to become CATION
- high ionization energy and high electron affinity means it has tendency to become ANION
- general electonegativity INCREASES FROM LEFT TO RIGHT and DECREASES FROM TOP TO BOTTOM in the periodic table
- mass of electron = 1/1840 x mass of proton
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Ionization Energy
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האנרגיה הדרושה לעקור אלקטרון מאטום נקראת אנרגית יוניזציה
- האנרגיה הדרושה להפוך אטום ליון
- ionized atom loses its electron
- FIRST IONIZATION POTENTIAL of an atom is the minimum energy needed to remove the highest-energy (outermost) electron from the neutral atom in the gaseous state
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MOLECULAR GEOMETRY AND CHEMICAL BONDING THEORY
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heteronuclear diatomic molecules
- molecules composed of two different nuclei
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VSEPR (valence-shell electron-pair repulsion model)
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linear 2
- 180 degree
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trigonal planar 3
- 120 degree
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Tetrahedral 4
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Tetrahedral 4
- 109 degree
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trigonal pyramidal 3 1
- 107 degree
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bent 2 2
- 105 degree
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trigonal bipyramidal 5
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trigonal bipyramidal 5
- 120 and 90 degree
- seesaw 4 1
- t-shaped 3 2
- linear 2 3
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octahedral 6
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octahedral 6
- 90 degree
- square pyramidal 5 1
- square planar 4 2
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dipole moment
- atoms with dipole movement have ל+ and ל- charges
- the movement is tend to move from weak electronegative atom to the strong atom
- Linear in AX2, Trigonal planar, Tetrahedral, Square planar, Trigonal bipyramidal, Octahedral have zero dipole movement
- Think then what kinds of molecules have dipole movements and how strong are they
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valence bond theory
- A bond forms when the following conditions are met
- 1. An orbital on one atom comes to occupy a portion of the same region of space as an orbital on the other. The two orbitals are said to overlap.
- 2. The total number of electrons in both orbitals is no more than two.
- hybrid orbitals
- I must write definitions in my own words!!
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VSEPR (valence-shell electron-pair repulsion model
- a model for predicting the shapes of molecules and ions in which valence-shell electron pairs are arranged about each atom so that electron pairs are kept as far away from one another as possible, thus minimizing electron-pair repulsions.
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dipole moment
- a quantitative measure of the degree of charge separation in a molecule
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valence bond theory
- an approximate theory to explain the electron-pair or covalent bond by quantum mechanics
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hybrid orbitals
- orbitals used to describe bonding that are obtained by taking combinations of atomic orbitals used to describe the isolated atoms
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sigma bond
- a bond that has a cylindrical shape about the bond axis
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Definitions
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VSEPR (valence-shell electron-pair repulsion model
- a model for predicting the shapes of molecules and ions in which valence-shell electron pairs are arranged about each atom so that electron pairs are kept as far away from one another as possible, thus minimizing electron-pair repulsions.
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dipole moment
- a quantitative measure of the degree of charge separation in a molecule
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valence bond theory
- an approximate theory to explain the electron-pair or covalent bond by quantum mechanics
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hybrid orbitals
- orbitals used to describe bonding that are obtained by taking combinations of atomic orbitals used to describe the isolated atoms
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sigma bond
- a bond that has a cylindrical shape about the bond axis
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pi bond
- a bond that has an electron distribution above and below the bond axis
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molecular orbital theory
- a theory of the electron structure of molecules in terms of molecular orbitals, which may spread over several atoms or the entire molecule
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bonding orbitals
- Molecular orbitals that are concentrated in regions between nuclei
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antibonding orbitals
- Molecular orbitals that are concentrated in regions other than between two nuclei
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homonuclear diatomic molecules
- molecules composed of two like nuclei
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heteronuclear diatomic molecules
- molecules composed of two different nuclei
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pi bond
- a bond that has an electron distribution above and below the bond axis
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molecular orbital theory
- a theory of the electron structure of molecules in terms of molecular orbitals, which may spread over several atoms or the entire molecule
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bonding orbitals
- Molecular orbitals that are concentrated in regions between nuclei
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antibonding orbitals
- Molecular orbitals that are concentrated in regions other than between two nuclei
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homonuclear diatomic molecules
- molecules composed of two like nuclei