-
Uses
-
fertlizers 76%
-
NPK
- nitrogen
- phosphorous
- potassium
- Chemicals 7%
- Plastics and Fibres 6%
- other uses 6%
- explosives 5%
-
Haber Process
- 200 atmosphers
- 450 C
- iron catalyst
-
72% of material not react first time
- recycled
-
Temperature &
Pressure on
yield
-
low temperature
- slow
- high yield
-
450 C
- compromise
- less made
- faster
- iron catalyst
- increases rate NOT yield
- N2 (g) + 3H2 (g) <---> 2NH3 (g) [deltaH = -92kJ mol-1]
-
Nitric Acid
-
Ostwald Process
-
stage 1
- platinum-rhodium gauze at 850C
- 4NH3(g) + 5O2(g) ---> 4NO (g) [nitrogen monoxide] + 6H2O(g)
- oxidation of ammonia
-
stage 2
- oxidation of nitrogen monoxide
- cooled (25C) and mixed with air
- 2NO(g) + O2(g) ---> 2NO2(g) [nitrogen dioxide]
-
stage 3
- nitrogen dioxide dissolved in water
- 4NO2(g) + O2(g) ---> 4HNO3 (aq) [nitric acid] + 2H2O (l)
-
properties
-
very soluble in water
- characteristic of weak alkali
- pungent smell
- colourless gas
- less dense than air
-
with hydrogen chloride
- produces thick white fumes