-
Addition
Polymerisation
-
ethene --catalyst & heat--> poly(ethene)
- long polymer chain
-
alkenes
-
make polymers
- very large molecules
- made up of monomers
- react with themselves
-
plastics
- difficult to dispose of
-
not biodegradable
- bacteria not decompose back into soil
-
burried in landfil
- filling up!
-
burnt
- toxic fumes
-
thermoplastics
- melted down and used again
-
intermolecular forces weak
- break on heating
- melted & remoulded
-
thermosetting plastics
- hard at high temperature
- UV sunlight may aid break down of some of them
-
intermolecular bonds strong
- interlinking covalent bonds
- heat
- whole structure breaks down
-
CO2 capture and formation of PPC
- energy.gov
- royal society of chemistry
- stephens mouldings website: plastic examples
-
recycling
- difficult
- separate out each type of plastic
-
Condensation
polymerisation
-
2 different monomers
- react
-
expel small molecule
- usually water
- hence condensation
-
Nylon
-
starting monomers
-
1,6-diaminohexane
- H2N(CH2)6NH2
-
hexanedioic acid
- HOOC(CH2)4COOH
-
amide link produced
-
nylon = polyamide
-
Terylene
-
starting reactants
- ethane-1,2-diol
- benzene-1,4-dicarboxylic acid
-
ester linkage
-
terylene = polyester