-
Temperature
-
inc. temperature
- inc. kinetic energy
- particles faster
- more collisions / second
- increased proprtion of effective collisions
- inc. rate
- NB same end point
-
Catalyst
- chemically unchanged at end of reaction
- increased rate
-
managanese (IV) oxide
- catalyst
- decomposition : hydrogen peroxide ---> water + oxygen
-
Surface Area
- inc. surface area
- inc. rate
- reaction only where particles collide
-
Concentration
- inc concentration
- inc. rate
- NB same end point
-
Equilibrium
- not rates but no where else to go
-
C (s) + O2 (g) ---> CO2 (g)
- CO2 can not be changed back
- can not be reversed
-
reversable
-
copper (II) sulphate
crystals
- CuSO4.5H2O (s) <--> CuSO4 (s) + 5H2O
- copper(II) sulphate crystals <---> anhydrous copper (II) sulphate + water
-
heat
- water lost
- white
-
add water
- blue
-
ethene / ethanol
- ethene + water <--heat & catalyst--> ethanol
- C2H4(g) + H2O (g) <--heat & catalyst --> C2H5OH (g)
-
equilibrium
- dynamic equilibrium
- moving equilibrium
- rate of formation = rate of decomposition
- rate of formation = rate of decomposition
-
dynamic equilibrium
- moving equilibrium
-
changing equilibrium position
- increase yield in industrial chemistry
- A (g) + 2B (g) <--> 2C (g) deltaH = +
-
concentration
- Add A and B
- Remove C
-
pressure
- increase
- 3 molecules on left only 2 on right
-
temperature
- increase
- reaction endothermic
-
catalyst
- NO!!!
- increases rate
- not affect position of equilibrium