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Deposit inhibitor
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Mechanism
- Threshold inhibition
- Crystal modification
- Sequestration
- Dispersion
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Types
-
Polymers
-
Silica
- Acrylic acid+Allyl hydroxy-propyl sulfonate ether
- Surfactants
- Borate
- Subtopic 2
-
Scale Inhibitor
- Threshold inhibition
- Crystal modification
- Sequestrants
-
Corrosion inhibitors
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Anodic
- Mechanism by interfering with anodic reaction
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Oxidising
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Mechanism
- promotes rapid oxidation of the metal surface
- they DO NOT require oxygen in order to function
- need minimum amount or else surface can loose protective layer and pitting with occur
- promote gamma iron oxide to form FeOOH
- Nitrites
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Non-oxidising
-
Mechanism
- require the presence of oxygen
- form salts of iron to ppte onto the surface
- chemisorb onto the oxide layer reducing ion permeability
- Iron salts of carbonate
- Ortbophospphates
- Molybdates
- Phosphonates
-
Cathodic
- Mechanism by preventing reduction of oxygen or electron transfer at the cathode
- Zinc based inhibitors
- Polyphosphate
- Carbonate
- Cathodic barrier films need physical and electrical impermeability to prevent oxygen from physically reaching the metal surface.
Both are needed to prevent oxygen reduction.
- Cathodic barrier films are catalysed by hydroxide produced by the cathodic reaction
- Localised high pH also cause ppte of hydroxides to form inhibitor film
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Bipolar Films
- Mechanism combination of both anodic and cathodic
- Azoles
-
Phosphonates
- PSO
- HEDP
- AMP
- PBTC
- Organic filming amines
-
Film Forming
- Azoles
- Thiazoles