-
Draw all VE for each atom
- Stable structure
if all electrons paired
and each atom has 8 electrons
around (8 electron rule)
- Split all bonds and count
the electrons for each atom
=> if no = no of VE, then no charge
- Assign all bonding electrons
to the atom with higher EN
=> we get the oxidation no
- Sometimes RESONANCE structures
are possible which stabilize
a charge, like in the nitrate ion
- Resonance structures stabilizes a molecule like ozone
-
All electrons repulse each other ("VSEPR")
=> we can estimate the 3D structure
- most common geometries
-
AO Hybridization
to explain single and
multiple bonds
-
Example: Carbon has 4 electrons, but they are not equal !
=> Combine 2s and 2p AO's together:
- For 4 single bonds in C, we need 4 equal AO's, half filled => sp3
- For 3 single bonds in C, we need to combine s+2xp, = sp2
one p-AO is left
- Common hybridisation
and structures
- sigma and pi bonds
and lone pairs
- 2 sigma, 2 pi bonds and l.p.