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What
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Types of MTx
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Pure sol-gel
- Gels
- Particles (Stöber)
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Hybrid MTx
- Type I
- Type II
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Nanostructured MTx
- Mesoporous Mtx
- Quantum dots
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Characterization
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Atomic scale
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X-ray Diffraction
- Crystal size
- Disorder
- XAS
- PDF
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Mesostructure scale
- SAXS
- N2 adsorption isotherms
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Origins
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Origins?
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Creation
- Scientific phenomenum
- Alkoxides chemistry
- Revival in the 80's
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Who?
- Jeff Brinker
- Jacques Livage
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Why
- Easy shaping
- Purity
- Room temperature
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Include organic & inorganic
- Compare with "Shake & bake"
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Where
- Ceramics
- Electronics
- Biomedical applications
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How
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The alkoxide route
- Alkoxides
- Hydrolysis
- Condensation
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The colloidal route
- Stability & reactivity
- Partial Charge model
- Prefabricated route